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This can be done in the second mission after fighting Baka. You will need to fight through enemies to escape the church and the area. The game will introduce you to molotovs and one of the enemies outside of the church will have molotovs to throw at you. Be sure to shoot him as he begins his throw, timing it right will cause him to set himself on fire. Now restart the checkpoint, or allow yourself to die and rinse and repeat 10 times.

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