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To get this trophy you must first unlock or purchase Captain Britain, Union Jack, Spitfire, Agent Carter and Mandarin (Trevor Slattery), their locations and costs are as follows:

- Agent Carter is given to you upon completion of Anger Management in Story Mode. Cost = N/A
- Captain Britain is found by completing his mission in Washington D.C. Cost = 250,000
- Mandarin (Trevor Slattery) is found by completing his mission on the beach of the Malibu Hub. Cost = 3,000 studs
- Spitfire token in found in the Sokovia Hub. Cost = 30,000 studs
- Union Jack token is found in the Shield Base. Cost = 75,000 studs

Once you have unlocked and purchase all 5 characters, switch to all of them and the trophy will unlock.

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