(1)First you will be going to the college of Winterhold, inside the Hall of Attainment. Talk to Enthir on the second floor. He sometimes can be tricky to find but he will be in that room. If not look in the bottom floor. He will sell you 2 Daedra hearts every two days.

(2) Shrine of Mehrunes Dagon, After the quest "Pieces of the Past" ( Started in Dawnstar) 2 Dremora will attack you, kill them and search them, they will have a Daedra heart each. Inside two more to kill.

(3) Next we have the Hall of the Vigilant, which is directly south of Dawnstar. Inside will be one Daedra heart on a plate. The place is pretty hidden so keep a look out.

(4) In Whiterun, go to the Jorroskr, in the living quarters (basement)as soon as you enter turn right and follow the hallway. There is a Daedra heart sitting on a plate.

(5) Majority of alchemist stores such as The White Phial and Arcadia's Caludron sell Daedra hearts, it's a rare occasion. Some general stores will sell Daedra hearts but this also is a rare occasion.